VIBRATIONAL SPECTRA OF CIS AND TRANS-2-BUTENES

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1966

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Ohio State University

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Infrared spectra in the range $250-4000 cm^{-1}$ in the gas, liquid, and matrix-isolated states and Raman spectra in the liquid state were measured for the following isotopically substituted 2-butenes: cis and trans- $C_{4}D_{8}$, and cis and trans- $CH_{3}CDCDCH_{3}$. While the assignments of earlier workers have been generally confirmed, these more extensive, higher resolution data have allowed a more complete assignment to be made especially for the methyl group modes. This work was funded under the Foundational Research Program of the Naval Ordnance Systems Command.

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Author Institution: Research and Development Department, U. S. Naval Propellant Plant

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