INVESTIGATION OF THE METHYLENE AMIDOGEN RADICAL USING THE CRDS TECHNIQUE

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2002

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Ohio State University

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Cavity ringdown spectroscopy (CRDS) was used to study room temperature chemical reactions of the methylene amidogen radical (CH2N). The radical was prepared by 193 nm photolysis of formaldoxime, CH2NOHCH2N+OH. CRDS signal from both CH2N and OH [A-X (1,0) band] was observed in the wavelength region 278-288 nm. By comparison of the OH and CH2N signals, absorption cross section of the CH2N was determined. To correct for the loss of OH radical by reaction, the rate constant of the reaction of OH with formaldoxime was measured, k(CH2NOH+OH)=2.510−12 molecule cm3s−1. Reaction of CH2N with stable molecules such oxygen, hydrogen and methane could not be observed and only an upper limit of the reaction rate constants, <1.010−15 molecule cm3s−1, could be derived. Self-recombination was the main removal process for the CH2N radical under the conditions of our experiment.

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Author Institution: Department of Chemistry, The Johns Hopkins University

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