DIFFERENTIAL REFLECTION SPECTROSCOPY: A DIRECT DETERMINATION OF LONG WAVELENGTH OPTICAL MODE FREQUENCIES IN POLAR CRYSTALS

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1987

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Ohio State University

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To the best of our knowledge, no simple scheme has been proposed for a direct determination of optical mode frequencies from observations of reflectivity, R, without detailed curve fitting. It is our purpose to suggest such a scheme. We shall work in the wavelength, λ, domain. We propose that the transverse optical wavelength (λTO) and Longitudinal optical wavelengths (λLO) correspond to those points where dR/dλ=0, is an extrema, that is where d2R/dλ2=0. In particular the λTOs correspond to points where d2R/dλ2=0 and dR/dλ<0 whereas the λLOs correspond to points a where dR/dλ=0 but dR/dλ>0. A simple heuristic argument shows that this method will work to the same extent that Changs1 method is valid. Differential reflection spectra of Al2O3.MgAl2O4.Al23O27N5(ALON) and Y2O3 will be presented. In most cases well defined peaks are obtained making the determination of the optical mode frequencies straight forward.

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1 I.F. Chang, et.al. Phys. Status Solidi 28, 663 (1968)


Author Institution: The Johns Hopkins University, Applied Physics Laboratory

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