OBSERVATION OF VIBRATIONALLY INDUCED DIPOLE MOMENTS IN TETRAHEDRAL MOLECULES

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1971

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Ohio State University

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Using the technique of electric deflection in a molecular beam, CCl., CF., and SiCl, have been observed to be polar in the $v_{3}$ excited vibrational states. The polar behavior results from a vibrationally induced dipole moment possible in certain types of degenerate vibrational states. This interpretation is confirmed by the dependence of the polar behavior on temperature and on isotopic substitution of the chlorine atoms.

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Present address of Annabel A. Muenter: Eastman Kodak Company, Rochester, New York 14650.""
Author Institution: Department of Chemistry, Harvard University; Bell Telephone Laboratories, Incorporated

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http://hdl.handle.net/1811/8798

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979