THE VIBRATIONAL SPECTRA OF SOME MONOSUBSTITUTED BENZENE DERIVATIVES OF GROUP VIA ELEMENTS

Rasheed, F. S.; Kimmel, Howard S.

THE VIBRATIONAL SPECTRA OF SOME MONOSUBSTITUTED BENZENE DERIVATIVES OF GROUP VIA ELEMENTS

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Date

1976

Authors

Rasheed, F. S.

Kimmel, Howard S.

Publisher

Ohio State University

Abstract

The vibrational frequencies for $(C 6 H 5) 2 S e$ , $(C 6 H 5) 2 T e$ , $(C 6 H 5) 2 S e 2$ , $(C 6 H 5) 2 T e 2$ , $(C 6 H 5 S) 2 H g$ , and $(C 6 H 5 S e) 2 H g$ have been completely assigned an were consistent with the vibrational assignments for $(C 6 H 5) 20$ , $(C 6 H 5) 2 S$ , and $(C 6 H 5) 2 S 2$ reported elsewhere. Further, whereas $(C 6 H 5) 20$ and to a lesser extent $(C 6 H 5) 2 S$ show vibrational spectra consistent with nonequivalence of the two phenyl rings attached to the central atom, the spectra of the other molecules show little evidence for such non-equivalency of the two phenyl rings. The vibrational assignments for $(C 6 H 5) 2 T e$ confirmed the linearity of the Gordy Rule plot of the t-vibration for Group VIA Elements.

Description

Author Institution: Chemistry Division, New Jersey Institute of Technology

URI

http://hdl.handle.net/1811/9694

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979

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