SPECTROSCOPY OF INORGANIC NITRATES.

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1967

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Ohio State University

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Computations of a Mulliken-Wolfsberg-Helmholtz type, carried to self-consistency of the density matrix, were performed for nitrate ion, nitrate ion-metal complexes, and aquated nitrate ion-metal complexes. Potential energy curves for the nitrate inversion were also generated and will be correlated with Walsh's rules and the spectroscopy of the ion. Solvent effects will also be discussed.

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Author Institution: Department of Chemistry, Louisiana State University

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