PHOTOLYSIS OF $CH_{3}COOD$ IN THE FIRST $^{1}(n,n^{*})$ BAND
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Date
1991
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Publisher
Ohio State University
Abstract
Following near-uv excitation of gas-phase acetic acid-d, nascent OD photofragments have been probed using laser fluorescence excitation. The partially deuterated parent species was chosen to examine the effect of moving the fragment center-of-mass away from oxygen, relative to the OH center-of-mass. Results will be compared to OH internal state distributions measured following $photolysis^{1}$ of $CH_{3}COOH$, to assess the dynamical changes resulting from isotope substitution.
Description
$^{1}S $. S. Hunnicutt, L. D. Waits, and J. A. Guest, J. Phys. Chem. 95, 562 (1991); 93, 5188 (1989).""
Author Institution: Department of Chemistry, University of Cincinnati
Author Institution: Department of Chemistry, University of Cincinnati