INFRARED INTENSITIES OF THE FUNDAMENTAL FREQUENCIES OF $CF_{3}Br$

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1956

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Ohio State University

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Absolute intensities have been measured for the fundamental bands of CF3Br, using the extrapolation technique of Wilson and Wells, at a total pressure of one atmosphere. These have been interpreted in terms of bond moments and derivatives, using normal coordinates calculated from the potential function of McGee, et al. (J. Chem. Phys., 21, 242 (1953)). While the sign ambiquity is not completely removed, there is one choice which seems most favorable. The relationship between these results and those for other CF3−x molecules will be discussed.

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Author Institution: Department of Chemistry, State University of Iowa; Department of Pure Physics, National Research Council

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http://hdl.handle.net/1811/7554

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1946-1959