OXYGEN-17 QUADRUPOLE COUPLING IN $OPF_{3}$ BY FOURIER TRANSFORM MICROWAVE SPECTROSCOPY
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Date
1986
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Ohio State University
Abstract
The $J = 1 \pm 0$ rotational transition in $^{17} OPF_{3}$ was measured by a pulsed supersonic nozzle FTMW spectrometer. This gave $B^{3}= 4491.420(3) MHz$ and $eqQ = -3.73(10) MHz$. The quadrupole coupling constant is consistent with substantial $\pi$-bond character in the phosphorus-oxygen bond based on the Townes \& Dailey model.
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Address: Department of Chemistry, University of Michigan, Ann Arbor, MI 48109
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