Absolute Intensity Measurements in $^{16}O^{12}C^{32}S$: the $\nu_{1} + \nu_{3}$ Region

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1994

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Ohio State University

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We have measured the absolute intensity of about 400 rotational of 6 bands of $^{16}O {^{12}}C {^{32}}S$ in the region between 25000 and $32000 cm^{-1}$. The measurements were made on spectra recorded at a resolution of $0.005 cm^{-1}$ using Bruker IFS120HR spectrometer. Five of the bands exhibit weak to strong Herman-wallis dependencies. Experimental details as well as the final result obtained including transition moments, band strength and Herman-Wallis corrections, will be presented. These results will be discussed in terms of the interactions between the energy levels observed in this energy range.

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Author Institution: Laboratoire de Chimie Physique Mol\'eculaire, C.P. 160/09 - Universit\'e Libre de Bruxelles; Laboratoire de Spectroscopie, Mol\'eculaire-Universit\'e Catholique de Louvain

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