Absolute Intensity Measurements in $^{16}O^{12}C^{32}S$: the $\nu_{1} + \nu_{3}$ Region

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1994

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Ohio State University

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We have measured the absolute intensity of about 400 rotational of 6 bands of 16O12C32S in the region between 25000 and 32000cm−1. The measurements were made on spectra recorded at a resolution of 0.005cm−1 using Bruker IFS120HR spectrometer. Five of the bands exhibit weak to strong Herman-wallis dependencies. Experimental details as well as the final result obtained including transition moments, band strength and Herman-Wallis corrections, will be presented. These results will be discussed in terms of the interactions between the energy levels observed in this energy range.

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Author Institution: Laboratoire de Chimie Physique Mol'eculaire, C.P. 160/09 - Universit'e Libre de Bruxelles; Laboratoire de Spectroscopie, Mol'eculaire-Universit'e Catholique de Louvain

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http://hdl.handle.net/1811/13004

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999