FAR-INFRARED SPECTRA AND RING-PUCKERING VIBRATION OF 1,3-DISILACYCLOBUTANE –$d_{0}$ AND -$d_{4}$
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Date
1975
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Ohio State University
Abstract
The far infrared spectra of $H_{2}SiSH_{2}CH_{2}$ and its $d_{4}$ analog have been recorded in the $20-100 cm^{-1}$ region. A large number of bands corresponding to the puckering mode were observed for each compound. The data are correlated with infrared combination bands and low-frequency Raman lines in order to obtain the potential energy function. A barrier of inversion of $88 cm^{-1}$ was determined.
Description
This work was supported by the Robert A. Welch Foundation.
Author Institution: Department of Chemistry, Texas A\&M University
Author Institution: Department of Chemistry, Texas A\&M University