LEVEL CLUSTERING IN E + F COMBINATION BANDS IN SPHERICAL TOP MOLECULES
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Date
1978
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Publisher
Ohio State University
Abstract
Clustering of octahedral and tetrahedral levels is shown to occur for a model Hamiltonian of the $\nu_{2} +\nu_{3}$ or $\nu_{2} + \nu_{4}$ combination band due to a Coriolis interaction. Cluster correlation diagrams are shown for cases where the pure Vibrational splitting Is both large and small compared to the Coriolis splitting. Approximate formulas are derived for the cluster levels in both cases.
Description
Author Institution: Los Alamos Scientific Laboratory