TEMPERATURE-DEPENDENCE OF AIR-BROADENING AND SHIFTS OF $O_{3}$ LINES

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Date

1993

Authors

Smith, M. A. H.
Rinsland, C. P.
Devi, V. Malathy
Benner, D. Chris

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Ohio State University

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Abstract

We have recorded high-resolution absorption spectra of ozone broadened by dry air at several temperatures between +23C and −63C using the Fourier transform spectrometer at the McMath-Pierce facility of the National Solar Observatory on Kitt Peak. The spectra cover the region from approximately 600cm−1 to 2700cm−1 at a resolution of 0.005cm−1. Broadening gas pressures varied from approximately 100 to 250 Torr. From these spectra we have determined air-broadening and line shift coefficients and their temperature dependences for a number of lines in the ν1 band. The broadening results are compared with previous measurements of the temperature-dependence of N2 and O2broadening coefficients in the ν3 band1−2. Analysis of additional lines in the ν1,ν2, and ν1+ν3 bands is in progress.

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1. M. N. Spencer, C. Chackerian, C. Flannery, and J.I. Steinfeld, Spectrochim. Acta 48A, 1273-1282 (1992). 2. M. N. Spencer, C. Chackerian, C. Flannery, and J.I. Steinfeld, J. Quant. Spectrosc. Radiat. Transfer, in press (1993).


Author Institution: Atmospheric Sciences Division, NASA Langely Research Center; Department of Physics, The College of William and Mary

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