THE ANTIFERROMAGNETIC $Mn_{2}$ Molecule

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1981

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Ohio State University

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Nesbet in 19641, calculated that Mn2 should be an antiferromagnetic molecule (1Σg+ lowest State) with an exchange interaction constant J =-4.1cm−1 It is here reported that this has been verified by electron-spin-resonance spectroscopy of the Mn2 molecule formed in solid krypton and xenon matrices at 4K by measurements at higher temperatures. The complexity of the spectra increase as the temperature rises, with each line split Into II distinct hyperfine components separated by 15 G and with relative intensities 1:2:3:4:5:6:5:4:3:2:1. This splitting is about one-half for that for single 55Mn atoms as expected for two exchange-coupled atoms. Tentative assignments indicate that J=−20cm−1 and that the zero-field-splitting in the S = 2 and S = 3 spin states are |D|≃ 0.14 and 0.07cm−1, respectively. Other research, suggested by these observations, will be mentioned. 1R.K. Nesbet, Phys, Rev. A135, 460 (1964).

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