ORIENTATION DEPENDENCE OF THE MAGNETIC CIRCULAR DICHROISM AND MAGENTIC CIRCULARLY POLARIZED EMISSION IN THE $^{4}A_{2{g}} \leftrightarrow ^{2}E_{g}$ TRANSITIONS IN $Cs_{2}GeF_{6}$:$Mn^{4+}$
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Date
1975
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Recently developed magnetic circularly polarized emission (MCPE) experiments give information about relaxed excited states and ground state vibrational levels that cannot be obtained from the more well-known magnetic circular dichroism (MCD) experiments. Furthermore, the orientation dependent of Zeeman effects in $U^{\prime}$ octahedral states give rise to orientation dependent MCD and MCPE spectra. In $Cs_{2}GeF_{6}:Mn^{4+}$ our high resolution MCD and MCPE spectra along the 111 and 100 directions give information about the various vibrational levels in the $^{4}A_{2{g}}$ and $^{2}E_{g}$ states.
Description
This work, was supported by a grant from the National Science Foundation.""
Author Institution: Department of Chemistry, University of Virginia; Department of Chemisrty, Louisiana State University
Author Institution: Department of Chemistry, University of Virginia; Department of Chemisrty, Louisiana State University