INTENSITIES IN RAMAN VIBRATIONAL SPECTRA

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1955

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Ohio State University

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The most recent bond polarizability method for the prediction of Raman intensities has been tested by calculating the relative intensitites of the E vibration of methane and the $A_{2}$ vibration of methylene chloride. The calculated and observed values differ by an order of magnitude. The result implies that the components of the bond polarizability tensor depend strongly on changes of interbond angles and the nature of the adjacent bonds.

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Author Institution: Department of Physics, University of Oklahoma

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