MICROWAVE AND MATRIX-INFRARED STUDY OF THE GAS-PHASE OZONOLYSIS OF $^{12}CH_{2} ^{13}CH_{2}$
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Date
1976
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Volume Title
Publisher
Ohio State University
Abstract
Besides well known products of the gas phase ozonolysis of ethylene, formic anhydride, glycolaldehyde, ethylene oxide and acetaldehyde have been detected by combined linear reactor infrared matrix- and microwave spectroscopy. Microwave and IR matrix spectra of products of $^{12}CH_{2}^{13}CH_{2}$ ozonolysis were identified in order to elucidate the reaction mechanism. The distribution of $^{13}{C}$-isotopic species was qualitatively determined. The implications of the results for the reaction mechanism will be discussed.
Description
Author Institution: Laboratory for Physical Chemistry, ETH