THE POLARIZED SINGLE-CRYSTAL SPECTRA AND ELECTRONIC STRUCTURE OF MAGNUS GREEN AND RELATED SALTS
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Date
1970
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The origin of the strong allowed out-of-plane transition found in the quartz ultra-violet region for $PtCl_{4}^{2-}$ and related square-planar complexes has not yet been totally resolved. Partially with the motivation of providing further experimental evidence on which to base this assignment, the polarized single-crystal reflection spectra of a series of Pd and Pt Magnus-type salts of the form ${[M{(NH_{3})}_{4}]}^{2+}{[MX_{4}]}^{2-}$, where M = Pt, Pd and X=Cl, Br, I, have been measured. These spectra and the absorption spectra derived from them will be presented and discussed in terms of current theory for planar complexes.
Description
Partial support has been provided by the National Institutes of Health for this research. Stephen I. Foster was a National Defense Education Act Fellow.
Author Institution: Department of Chemistry, New Mexico State University
Author Institution: Department of Chemistry, New Mexico State University