THE ABSORPTION SPECTRUM OF $Kr_{2}$ IN THE VACUUM-UV REGION

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1973

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Ohio State University

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The absorption spectrum of the Kr2 molecule was photographed in the 1040 - 1300 \AA region using a 6.65 m vacuum spectrograph, in the second order, and the argon continuum as a background source. Eight band systems, four well-developed and four rather fragmented, were classified. A vibrational analysis was performed for the former four systems and the molecular constants obtained for the ground state and for some of the upper states will be presented. In general, the spectrum of Kr2 is very similar to that1 of Ar2. The spectroscopically determined dissociation energy of the ground state is in good agreement with the value from molecular beam scattering experiments.2

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1 Y. Tanaka and K. Yoshino, J. Chem. Phys., 53, 2012 (1970). 2 K. K. Docken and T. P. Schafer, Preprint.


Author Institution: Air Force Cambridge Research Laboratories

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