INFRARED SPECTRA OF THE FLUOBORATE ION IN ALKALI HALIDE MATRICES

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1963

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Ohio State University

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“The infrared spectra of the $BF_{4}{^{-}}$ ion have been measured in dilute solid solutions in various alkali halide pellets. Using small grating spectrometers, careful measurements have been made of the dependence of the vibrational frequencies on the nature of the host lattice and on the temperature. Tetrahedral selection rules appear to be strictly followed, indicating that the ion is symmetrically orientated with respect to the octahedral fields of the host lattices. A comparison of these results with those on the similar perchlorate ion previously reported at this $Symposium^{1}$ will be given.”

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$^{1}$Julius L. Mack, Albert S. Tompa and George B. Wilmot, Symposium on Molecular structure and Spectroscopy. The Ohio State University, Columbus, Ohio, 1960.
Author Institution: Research and Development Department, U.S. Naval Propellant Plant

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http://hdl.handle.net/1811/8255

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969