SPECTROSCOPY OF THE RYDBERG STATES OF XeKr IN THE $68 000 CM^{-1}$ REGION
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Date
1993
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Volume Title
Publisher
Ohio State University
Abstract
The laser induced fluorescence spectrum of XeKr, prepared in a free-jet expansion, was obtained near the $Xe 6s[3/2]^{\circ} (J=1) <- {^{J}}S_{0}$ transition $(68045.66 cm^{-1})$. Transitions to three electronic states were identified within a $300 cm^{-1}$ range. Complex vibrational structure in the discrete spectra is attributed to an avoided crossing between two $\Omega = 1$ states. Bound-free transitions were also observed when exciting to repulsive states that produce an excited $Xe 6s[3/2]^{\circ} (J=1)$ atom. Spectroscopic constants and approximate potentials will be presented.
Description
Author Institution: Department of Pure and Applied Sciences, The University of Tokyo; Department of Chemistry, Massachusetts Institute of Technology