MICROWAVE MEASUREMENTS OF A DEUTERIUM ISOTOPE EFFECT ON HALOGEN QUADRUPOLE COUPLING IN METHYL HALIDES

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1978

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Ohio State University

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The J=1←0 rottional transitions in CH379Br,CH381Br,CD379Br and CD381Br were measured by standard microwave techniques using a C-band wavequide Stark cell. Some transitions were also measured using a beam maser spectrometer. Analysis of the data indicates a reduction in Br quadrupole coupling strengths when the methyl group is deuterated. This is in agreement with previous work on methyl chloride. Possible vibrational effects will be discussed.""

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Author Institution: Department of Chemistry

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http://hdl.handle.net/1811/10680

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979