THE BAND SPECTRUM OF THE GaH MOLECULE

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1960

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Ohio State University

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“An extensive emission system of GaH, in the region 5200-6400 \AA, has been obtained from a King furnace containing gallium metal and hydrogen at 1500∘C;. Eight bands have been measured and analyzed on the assumption that they arise from a 3ΠX1Σ transition.1 The following constants have been determined (cm−1): [FIGURE] Under the same conditions, a diffuse band system is observed between 4220 \AA and 4850\AA1. The vibrational differences of the lower state have been found to agree with those of the ground state given above. The bands appear to be double-headed consistent with a1Π; upper state.1

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Coefficient of (v+1/2)1 in expression for Br. 1 H. Neuhaus, Arkiv, fur Fysik 14, 551 (1959), who also analyzed the 0-0 bands of the 3Πo1Σ and 3Π11Σ systems.


Author Institution: Department of Chemistry, Vanderbilt University

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