FORCE CONSTANT CORRELATIONS FOR $CH_{3}XH_{3}$ MOLECULES.
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Date
1967
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Ohio State University
Abstract
An investigation of the nature of ``group vibrations'' has been made by means of comparisons of the hybrid orbital force constants of $CH_{3}SiH_{3}, CH_{3}GeH_{3}$ and $CH_{3}SnH_{3}$. Empirical relationships have been formulated which permit the transfer of force constants between the molecules of this series using the C-H and X-H bond lengths as the only parameters. Some preliminary results indicate that these empirical relationships can be extended to include molecules not in the $CH_{3}XH_{3}$ series.
Description
Author Institution: Department of Chemistry, Brooklyn College