SPECTROSCOPY OF THE $C^{1}\Pi- A^{1}\Delta$ TRANSITION OF $NH-Ne^{a}$

Thumbnail Image

Files

2001-RH-07.jpg (139.11 KB)

Date

2001

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

The NH-Ne van der Waals complex has been observed in conjunction with the C1Π−A1Δ transition of NH. Low resolution LIF spectra (0.5cm−1 linewidth) exhibit at least three vibronic bands of the complex in the region of the monomer 0- 0 band. The complex bands are spread over a region approximately 30cm−1 wide. The lowest energy band is red-shifted relative to the monomer, indicating that the van der Waals bond strengthens on electronic excitation. Spectra recorded at higher reso lution (0.08cm−1) show congested rotational structure. Analyses of these data and spectra for ND-Ne will be reported.

Description

aWork supported by National Science Foundation.


Author Institution: Emory University; Department of Chemistry, Emory University

Keywords

Citation

URI

http://hdl.handle.net/1811/20171

Collections

Abstracts of OSU International Symposium on Molecular Spectroscopy 2000-2009