THE PURE ROTATIONAL SPECTRUM OF ZnS (X$^{1}\Sigma^{+})$

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2009

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Ohio State University

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Millimeter-wave direct-absorption techniques have been used to measure the pure rotational spectrum of ZnS (X1Σ+). This work is the first spectroscopic study of ZnS in the gas phase. This molecule was produced by the reaction of zinc vapor and H2S under DC discharge conditions. Eight rotational transitions were recorded for four stable zinc isotopologues of ZnS in the v = 0 state, and data were also obtained for ^{64}ZnSand66ZnS in the v = 1 state. The data have been analyzed and spectroscopic constants and equilibrium parameters have been determined. The equilibrium bond length of ZnS was established to be 2.0464 \AA, as compared to 1.7047 {\AA} for ZnO.

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Author Institution: Department of Chemistry, Department of Astronomy, and Steward Observatory, University of Arizona, Tucson, AZ, 85721

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