THE DETERMINATION OF MOLECULAR POLARIZABILITY ANISOTROPIES BY MICROWAVE SPECTROSCOPY.

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1967

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Ohio State University

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By use of a special parallel-plate microwave absorption cell capable of sustaining very high, uniform electric fields, very accurate Stark effect measurements have been made for several molecules. Among the molecules studied have been NNO and methylacetylene, and for these molecules it has been possible to determine their polarizability anisotropy. The values obtained are 3.15×10−24cm3 and 2.7×10−24cm3, respectively. Also the previously reported data for OCS have been refined and a value for the polarizability anisotropy of 4.5310−24cm3 has been calculated.

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Author Institution: Chemistry Department, Harvard University; McDonnell Research Division McDonnell-Douglas Corporation, St. Louis, Missouri; Chemistry Department, Princeton University Princeton, New Jersey, 08540.

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