TORSIONAL EXCITATION IN O-H STRETCH OVERTONE SPECTRA OF ETHYL HYDROPEROXIDE CONFORMERS
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Date
2011
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Photoacoustic spectra at 3-6 quanta of O-H stretch show features attributed to torsion about the O-O bond and to distinct contributions from two conformers. Laser-induced fluorescence detection of OH radicals demonstrates unimolecular dissociation from some vibrationally and torsionally excited states.
Description
Author Institution: Chemistry Department, Smith College, Northampton, MA 01063