THE SPECTRA OF TETRAHEDRAL INORGANIC COMPLEXES AT $4^{\circ}K$.

Loading...
Thumbnail Image

Date

1966

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

The spectra of $MnCl_{4}{^{2-}}$, and $CoCl_{4}{^{2-}}$ and $NiCl_{4}{^{2-}}$ have been examined in single and mixed crystals with $ZnCl_{4}{^{2-}}$ at $4^{\circ}K$ using polarized light. The importance of nuclear distortions from perfectly tetrahedral symmetry as well as the effects of spin-orbit coupling and some finer effects of electronic repulsion in the interpretation of these spectra will be discussed.

Description

Author Institution: Chemistry Department, University of Michigan; Chemistry Department, Hull University Hull Yorks

Keywords

Citation