ROTATIONAL CONFORMERS OF GROUP VI (Cr, Mo, and W) METAL BIS(TOLUENE) $SANDWICH$ COMPLEXES
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Abstract
Transition metal bis(arene) sandwich complexes may adopt eclipsed or staggered conformations due to the aromatic ring rotations about the metal-arene axis.
Description
B.S.~Sohnlein, S.~Li, and D.S.~Yang, J.~Chem.~Phys. 123, 214306 (2005); B.S.~Sohnlein and D.S.~Yang, J.~Chem.~Phys. 124, 134305 (2006)S.Y.~Ketkov, H.L.~Sezle, and F.G.N.~Cloke, Angew.~Chem.~Int.~Ed. 46, 7072 (2007) and references therein.
Author Institution: Department of Chemistry, University of Kentucky, Lexington, KY 40506-0055