FEMTOSECOND CORRELATION SPECTROSCOPY

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2003

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Ohio State University

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We developed a kinetic-energy resolved time-of-flight mass spectrometry with femtosecond time resolution. The correlation of time, speed, orientation and state of reaction products was obtained. With these four resolution(s), a variety of chemical reactions was studied and new phenomena were discovered. Here, the classic example of bimolecular chargetransfer reactions of benzene with iodine and iodine monochloride will be given in detail.

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Author Institution: Departments of Physics, Chemistry and Biochemistry, The Ohio State University; Laboratory for Molecular Sciences, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology

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