THE PURE ROTATIONAL SPECTRUM OF CHLORINE NITRATE

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Date

1999

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Ohio State University

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Chlorine nitrate is a molecule of intermediate size whose infrared spectrum is partially resolvable in the Doppler limit. Its Doppler-limited pure rotational spectrum in the microwave is correspondingly dense, not only because of its relatively small rotational constants, but also because it has a number of relatively low-lying vibrational modes. We have recorded this complex spectrum in the microwave spectral region with a FASSST spectrometer. We will report analysis of both ground and excited vibrational states in both the $^{35}Cl$ and $^{37}Cl$ species.

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Author Institution: Department of Physics, The Ohio State University; Department of Physics and Chemistry, University of South Alabama; Department of Physics, The Ohio State University

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