REFLECTION SYMMETRIES OF LINEAR-MOLECULE ROVIBRONIC LEVELS
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Abstract
Coriolis forces break the infinite-fold axis of symmetry of a linear molecule, but leave a residual plane of symmetry. Thus the rovibronic (or spin.rovibronic) wavefunctions can be classified according to their behavior under reflection of the vibronic (or spin.vibronic) variables in this plane. The orientation of the plane depends on the coupling case. In Hund's case (a) or (e) the plane is through the molecular axis normal to the perpendicular component of the angular momentum J, while in Hund's case (b) it is normal to the perpendicular component of N. The former gives an exact symmetry classification equivalent to the
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Author Institution: Herzberg Institute of Astrophysics, National Research Council of Canada