Assignment of the $\nu_{1}+\nu_{2}$ and $\nu_{2}+\nu_{3}$ bands of the high resolution $^{14}NH_{3}$ FTS absorption spectra

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1987

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Ohio State University

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The Fourier transform absoption spectra of $NH_{3}$ with a resolution of $0.005 cm^{-1}$ were recorded at Laboratoire D'Infrarouge of Universite de Paris-Sud. The assignment of the $\nu_{1}+\nu_{2}$ and $\nu_{2}+\nu_{3}$ bands of $NH_{3}$ has been carried out for the J value as high as 13. The inversion-rotational energy levels of the ground states of $^{14}NH_{3}$ has been calculated. These energy levels are compared with the best previous $work^{(1)}$ which shows an agreement within $0.001 cm^{-1}$.

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(1) S. Urban. Romala D'Cunha, K. Naraharl Rao, and D. Papousek, Canad. J. Phys. 62, 1775-1791 (1984).
Author Institution: Department of Physics, The Ohio State University

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