SPECTROSCOPY OF THE NO-Ar COMPLEX IN THE VICINITY OF THE $3p\leftarrow X^2\Pi$ TRANSITIONS IN NITRIC OXIDE
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Date
2013
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Publisher
Ohio State University
Abstract
Spectra of the NO-Ar complex have been recorded using REMPI spectroscopy in the region corresponding to transitions to the $3p$ Rydberg states in uncomplexed NO. Additionally, spectra have been simulated using $ab~initio$ techniques with the aim of better understanding this region, as previous favourable results have been obtained using a similar approach for the $3s$ Rydberg state, \textbf{129}, 244303 (2008)}. Excellent agreement with the REMPI spectra is seen for the $3p \pi$ state simulation. Results on the $3p \sigma$ state will be discussed, along with extension to other NO-Rare Gas complexes.
Description
Author Institution: School of Chemistry, University Park, University of Nottingham, NG7 2RD, United Kingdom; Department of Chemistry, University of Maryland, College Park, MD 20742