HIGH RESOLUTION MOLECULAR-BEAM LASER SPECTROSCOPY OF STRONTIUM MONOFLUORIDE $(SrF)^{\ast}$

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1989

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Ohio State University

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The laser induced fluorescence spectrum of the red A2ΠX2Σ system of SrF has been recorded. Typical line widths of 20MHz are obtained with the laser beam crossing the molecular beam orthogonally. Each rotational line of the 88SrF main isotope and 86SrF lesser isotope is split into two components by the magnetic hyperfine interaction between the unpaired electron and the 19F nuclear spin of 1/2. The rotational line assignment of this band was confirmed by the rf labelling method (1), using previously measured ground state splittings (2). In addition, with our excellent S/N ratio, it was possible to record many lines from the much less abundant isotope 87SrF, clearly showing hyperfine structure due to the 87Sr nuclear spin of 9/2 as well as the hfs due to the 19F with its spin of 1/2. Efforts to measure the ground state hyperfine splitting of 87SrF by the rf-laser double resonance method are currently underway.

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This research was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, under contract W-31-109-ENG-38. (1) W.J. Childs, Z. Phys. D 7, 107-112 (1987) (2) W.J. Childs, L.S. Goodman, and I. Renhorn, J. Mol. Spectrosc. 87, 522-533 (1981)


Author Institution: Physics Division, Argonne National Laboratory

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