DOPPLER SPECTROSCOPY OF HOCl IN THE $7000 cm^{-1}$ REGION
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Date
1992
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The spectrum of HOCl in the $6700-7230 cm^{-1}$ region has been recorded at $0.01 cm^{-1}$ resolution (Doppler limits $0.013 cm^{-1}$) on a Bomem DA3.002 Fourier Transform spectrometer. The sample was prepared by admitting $Cl_{2}$ gas into an evacuated flask containing a slime of red mercury oxide and water scattered on the walls. The total pressure was 20 Torr and the pathlength through the multiple reflection cell was 6 m. The $2\nu_{1}$ band ($7038.7 cm^{-1}$) had been observed before [1] at low resolution, and a complete analysis has been carried out for the first time. Work on other overtone and combination bands is on the way.
Description
[1] K. Hedberg and R.M. Badger, J. Chem. Phys. 19 508-509 (1951).
Author Institution: Dipartimento di Chimica-Fisica e Inorganica, Viale Risorgimento; Instituto de Estructura de la Materia, C.S.I.C.
Author Institution: Dipartimento di Chimica-Fisica e Inorganica, Viale Risorgimento; Instituto de Estructura de la Materia, C.S.I.C.