ZEEMAN EFFECT IN THE 2782 {\AA} BAND OF HCP
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Date
1972
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The Zeeman effect in the 2782.22 {\AA} band of HCP has been observed and indicates the excited state is $^{3} \Delta_{1}$. A formula is derived for a $^{3} \Delta_{1}$ state, intermediate between case (a) and case (b), which expresses the Zeeman splitting as a function of J and the spin-orbit coupling constant. By applying this formula the spin-orbit coupling constant is found to be +22.3 or -$16.0 cm^{-1}$, depending on whether the $^{3} \Delta $ state is normal or inverted. The rotational constant and band origin for these two cases are also computed.
Description
Author Institution: Department of Chemistry, University of Illinois