INVESTIGATION ON REVERSE WATER-GAS SHIFT OVER La$_2$NiO$_4$ CATALYST BY CW-CAVITY ENHANCED ABSORPTION SPECTROSCOPY DURING CH$_4$/CO$_2$ REFORMING

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Reverse water-gas shift (RWGS) reaction over La2NiO4 catalyst was investigated during CH4/CO2 reforming by continuous wave (cw) cavity enhanced absorption spectroscopy (CEAS), a sensitive absorption technique. A cw-diode laser with wavelength in the 1.3 μm region and an optical cavity consists of a pair of high reflectivity mirrors (0.99995) were used in the experiment. Absorption lines of the ΔJ=0 (Q branch) rotational transitions of the 2$_0^13_0^1$ vibrational transition of CH4 near 7510 cm−1, and the J=5,Ka=0,Kc=5 to J=6,Ka=2,Kc=4 rotational transition of the 1$_0^13_0^1$ vibrational transition of H2O near 7511.29 cm−1 were monitored. The results indicated that the RWGS reaction promoted the conversion of CO2 and decreased the partial pressure of hydrogen. Our CEAS result confirms that the conversion of CO2 is always 3-5% higher than CH4 due to RWGS reaction. In addition, the effect of reaction temperature on RWGS was studied. The work described here was supported by a grant from the Research Grants Council of Hong Kong SAR, China (Project No. HKU7101/02P)

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Author Institution: Department of Chemistry, Tianjin University, Tianjin 300072, P.R. China and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong; Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong; Department of Chemistry and Center for Surface Analysis and; Research, Hong Kong Baptist University, Kowloon Tong, Hong Kong

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