ELECTRONIC SPECTROSCOPY OF RARE GAS ISOLATED $I_{2}$ AND IBr

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1988

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Ohio State University

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The electronic spectroscopy of I2 and IBr, isolated in solid rare gas matrices has been studied using time and wavelength resolved fluorescence techniques. Argon isolated I2, excited at a wavelength of 193 nm, showed a broad feature at about 380 nm, that has a very short life-time (= 20 ns). This transition has been tentatively assigned as the D(3Π2g)−A(3Π2u) system. Ar, Kr and Xe isolated IBr, excited at a wavelength of 532 nm, exhibited both A(3Π1)−X(1Σ) and A(3Π2)−X(1Σ) systems. The life-times of these transitions decrease with increasing atomic number of the host. Spectral and temporal analyses will be discussed.

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Work supported by AFOSR under grant 85-0210


Author Institution: Department of Chemistry, Enory University

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