IS PYRIMIDINE AN INTERMEDIATE STATE MOLECULE?

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1984

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Ohio State University

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The S1(1B1)←S0(1A1) transition in pyrimidine has been investigated. High resolution laser induced fluorescence spectra were obtained by crossing a well collimated molecular beam with UV radiation of an intra-cavity frequency doubled ring laser. The extreme resolution enabled us to observe the molecular eigenstates of the excited electronic state. Most of the spectral features arising from the S1 state could be interpreted in terms of a slightly perturbed axis switched asymmetric rotor spectrum. Perturbations are found both in the energy levels of the S1 state and in the relative intensities of the transitions. This is in agreement with the much smaller background triplet level density in pyrimidime as compared to pyrazine1. Single level lifetime measurements have been carried out for rotational states up to J=4. The results suggest a lengthening of the lifetimes of the excited state with increasing values of K. The question put in the title will be discussed.

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1 B.J. van der Meer, H. Th. Jonkman, J. Kommandeur, W.L. Meerts and W.A. Majewski Chem. Phys. Lett. 92 (1982) 565


Author Institution: Fysisch Laboratorium, Katholieke Universiteit; Herzberg Institute of Astrophysics, National Research Council of Canada; Laboratory of Physical Chemistry, University of Groningen

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