HIGH RESOLUTION LIF SPECTROSCOPY OF THE Ar.NO COMPLEX

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2000

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Ohio State University

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The $\tilde{A}\leftarrow \tilde{X}$ transition in ArNO has been recorded by high-resolution LIF spectroscopy. The work carries on a study of this complex by REMPI and ZEKE $spectroscopy^{a}$. Spectra have been recorded of the origin region, plus a region to higher energy, that has previously been attributed to stretch and stretch-bend combination bands. Progress in the analysis of the spectra will be reported; in particular, the previous deduction that the $\tilde{A}$ state of ArNO is linear (on average) at the zero-point, but bent (on average) at higher energies will be examined.

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$^{a}$A. M. Bush, J. M. Dyke, P. Mack, D. M. Smith and T. G. Wright, J. Chem. Phys. 108, 406 (1998).
Author Institution: School of Chemistry, Physics and Environmental Sciences, University of Sussex; Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University

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