HIGH RESOLUTION, ELECTRONIC SPECTROSCOPY OF THE RARE GAS (Ne, Ar, Kr) $\bullet$SH/D VAN DER WAALS COMPLEXES
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Date
1994
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Ohio State University
Abstract
The rotationally resolved, jet-cooled, electronic spectra of the SH/D rare gas complexes, Rg $\ast$ SH/D(Rg = Ne, Ar, Kr) have been recorded. The complexes were produced by the UV photolysis of small percentage mixtures of either $H_{2}S$ or $D_{2}S$ in He with the appropriate rare gas and then probed via LIF with a pulse amplified cw ring dye laser. We were able to resolve ($\approx$ 300 MHz lasser linewidth) both fine and hyperfine components of these complexes. Data for both pure van der Waals stretch bands as well as bend-stretch combination bands have been recorded for each complex. The analysis of these spectra will be presented and discussed.
Description
Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University