THE $\nu_{7}$ AND $\nu_{6}$ BAND SYSTEMS OF CARBON SUBOXIDE

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1990

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Ohio State University

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The analysis of the FIR spectrum of $C_{3}O_{2} (1)$ has been completed. Bands involving excitation of up to 8 quanta of the low frequency bending mode $\nu_{7}$ have been analysed. The results will be presented. The first contribution serves as a basis for further analysis of the IR spectrum of $C_{3}O_{2}$ in the region of the $\nu_{6}$ fundamental, started four years ago (2). For this purpose, a new spectrum has been recorded from 520 to $580 cm^{-1}$ at $-60^{\circ}C$ with twice the resolution used previously, i.e. $0.002 cm^{-1}$. The analysis has been extended and preliminary results will be presented.

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(1) J.W.C. Johns and J. Vander Auwera. Proceedings of the 44th Symposium on Molecular Spectroscopy, p. 143 (1989). (2) P. Jensen and J.W.C. Johns, J. Mol. Spectrosc. 118, 248-266 (1986).
Author Institution: Laboratoire de Chimie Physique Mol\'eculaire, Universit\'e Libre de Bruxelles CP.160, 50 av.

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