MICROWAVE ROTATIONAL SPECTRUM AND INTERNAL ROTATION IN METHYL MERCAPTAN

Loading...
Thumbnail Image

Date

1970

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

Some years ago Kojima and $Nishikawa^{1}$ first studied the microwave rotational spectrum of methyl mercaptan. We have extended their study to higher frequency in order to determine improved molecular structure, internal rotation potential coefficients, and vibration-internal rotation interaction terms. Most of the measurements have been made on a conventional Stark-modulated spectrometer. However, several lines have been assigned by the technique of three level microwave double resonance. The internal rotation problem has been formulated in a slightly different form for the analysis.

Description

$^{1}$a) T. Kojima and T. Nishikawa, J. Phys. Soc. Japan, 12, 680 (1957); b) T. Kojima, ibid. 15, 1284 (1960).""
Author Institution: Physics Department, Texas Technological University

Keywords

Citation