SEP SPECTRA OF $SCCl_{2}$
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Date
2003
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Ohio State University
Abstract
Stimulated emission pumping spectra with $0.3 cm^{-1}$ resolution provide a means of studying intramolecular vibrational energy redistribution (IVR). The $\tilde{A}(^{1}A_{2}) \to \tilde{X}(^{1}A_{1})$ transition of $SCCl_{2}$ from several different origins maps out the $7000-8000 cm^{-1}$ region in the ground state. An analysis of approximately 200 features in this region exhibits clumping of spectral features which can provide information about the fine structure of IVR.
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Author Institution: Department of Chemistry, University of Illinois at Urbana-Champaign