RESONANCE RAMAN INTERFERENCE IN LINEAR POLYENES
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Abstract
In centrosymmetric chromophores, such as linear polyees, approximately half of the electronic excited state manifold is inaccessible from the ground state by conventional absorption spectroscopy because of parity selection rules. However, the presence of such hidden'' excited states can sometimes be inferred from preresonance Raman excitation profiles. As the excitation radiation is tuned through the appropriate energy range, vibronic coupling between the state of interest and nearby allowed'' electronic States will produce interference effects in the ground state scattering intensity. Thrash,
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Author Institution: Department of Chemistry, Michigan State University