INTRACAVITY LASER ABSORPTION SPECTROSCOPY OF PLATINUM NITRIDE IN THE NEAR INFRARED

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2013

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Ohio State University

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Abstract

The (2,0) band of the $A^{2}\Sigma^{-}$ - $X^{2}\Pi_{1/2}$ electronic transition of PtN has been recorded using intracavity laser absorption spectroscopy. Transitions from $^{194}PtN$, $^{195}PtN$, and $^{196}PtN$ isotopologues are observed, as well as the nuclear hyperfine splitting due to $^{195}Pt$ with I=1/2. The results of the analysis will be presented and compared with ab initio calculations.

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Author Institution: Department of Chemistry, Southern Illinois University, Edwardsville, IL 62026-1652; Department of Chemistry, University of Missouri, St Louis, MO 63121-4499

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