``COMPLETE'' GROUND STATE ROTATIONAL CONSTANTS OF $CH_{3}D$ FROM PERTURBATION ALLOWED TRANSITIONS IN THE $2\nu_{6}$ BAND

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1981

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Ohio State University

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The highly accurate ground state constants previously determined1 from an analysis of allowed transitions in the ν2 band are augmented with values for AOBO and DOK. The latter were determined via ground state combination differences between allowed and perturbation allowed transitions in the parallel and perpendicular components of the 2ν6 band. These ground state differences were obtained for levels with ΔJ′‘−0 and Δk′‘=±3.

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Supported by the Monticello Foundation administered by the California Institute of Technology. 1 C. Chackerian, JR., and G. Guelachvili, J. Mol. Spectrosc. 84, 447-456 (1980).


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