``COMPLETE'' GROUND STATE ROTATIONAL CONSTANTS OF $CH_{3}D$ FROM PERTURBATION ALLOWED TRANSITIONS IN THE $2\nu_{6}$ BAND

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Date

1981

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Ohio State University

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The highly accurate ground state constants previously $determined^{1}$ from an analysis of allowed transitions in the $\nu_{2}$ band are augmented with values for $A_{O}-B_{O}$ and $D_{O}^{K}$. The latter were determined via ground state combination differences between allowed and perturbation allowed transitions in the parallel and perpendicular components of the $2\nu_{6}$ band. These ground state differences were obtained for levels with $\Delta J’‘- 0$ and $\Delta k’‘ = \pm 3$.

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$^{*}$ Supported by the Monticello Foundation administered by the California Institute of Technology. $^{1}$ C. Chackerian, JR., and G. Guelachvili, J. Mol. Spectrosc. 84, 447-456 (1980).
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