ZEEMAN SPLITTING OF THE $A^{1}\Sigma^{+}_{u} - b^{3}\Pi_{u}$ PERTURBED LEVELS OF $^{6}Li_{2}$
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Date
1986
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Ohio State University
Abstract
The $^{6}Li_{2} A^{1}\Sigma^{+}_{u} (v=2,J=33)$ level is spin-orbit perturbed by the $b^{3}\Pi_{u} (v=9, F_{1e}, N=32)$ $level. ^{1}$ We have studied the effects of magnetic fields up to 5 kG on these perturbed levels using magnetic rotation spectroscopy and sub-Doppler polarization spectroscopy to observe the zero-field separation, Zeeman splittings, and intensity changes of the $(A^{1}\Sigma^{+}_{u}; b^{3}\Pi_{u}) \leftarrow X^{1}\Sigma_{g}^{+}$ spectra. Different M components were selectively observed with different orientations of the magnetic field relative to the laser polarization.
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$^{1}$X. Xie and R. W. Field, Chem. Phys. 99, 337 (1985). Address: Department of Chemistry, Davey Laboratory, The Pennsylvania State University, University Park, PA 16802.
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